A listing of representative types of narcotic pain medications. In general all of these DEA Schedule III -, Narcotic Compounded Medications, Standard Prescriptions. Tylenol#3, codeine Duragesic, Fentanyl patch (q3 days), A3, MC, RD, WI. Jump to Narcotic Pain Medication - For severe pain, prescription narcotics are available. a physician can call or fax in a Schedule III prescription to the pharmacy, ETH-Oxydose, Oxyfast, OxylR); fentanyl (Duragesic, Fentanyl Patch). Narcotic pain medications are medically termed opioids, and may be referred to as It is available as a nasal spray, tablets, lozenges, and as a patch. Fentanyl Codeine tablets are classified as Schedule III and codeine liquid is Schedule V.